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Rampage Insecticide - Water dispersible granules (WG) Safety data sheet According to 1907/2006/EC (REACH), 2015/830/EU SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Local Poisons Information Centre Emergency telephone number: 1.4 Sapec Agro, S.A. Avenida do Rio Tejo, Herdade das Praias 2910-440 Setúbal - Setúbal - Portugal Phone.: +351265710100 - Fax: +351265710105 [email protected] www.sapecagro.pt Details of the supplier of the safety data sheet: 1.3 Uses advised against: All uses not specified in this section or in section 7.3 Relevant uses: Fungicide for agricultural use. For professional user only. Relevant identified uses of the substance or mixture and uses advised against: 1.2 Rampage Insecticide - Water dispersible granules (WG) Product identifier: 1.1 SECTION 2: HAZARDS IDENTIFICATION Label elements: 2.2 Acute Tox. 4: Acute toxicity if swallowed, Category 4, H302 Aquatic Acute 1: Hazardous to the aquatic environment, acute hazard, Category 1, H400 Aquatic Chronic 1: Hazardous to the aquatic environment, long-term hazard, Category 1, H410 Resp. Sens. 1: Sensitisation, respiratory, Category 1, H334 Classification of this product has been carried out in accordance with CLP Regulation (EC) No 1272/2008. CLP Regulation (EC) No 1272/2008: Classification of the substance or mixture: 2.1 Product fails to meet PBT/vPvB criteria Other hazards: 2.3 Chlorpyrifos (ISO); 4,4´-methylenediphenyl diisocyanate, isomers and homologues Substances that contribute to the classification EUH204: Contains isocyanates. May produce an allergic reaction EUH208: Contains 2,2´-iminodi(ethylamine). May produce an allergic reaction EUH401: To avoid risks to human health and the environment, comply with the instructions for use SP1: Do not contaminate water with the product or its container Supplementary information: P101: If medical advice is needed, have product container or label at hand P102: Keep out of reach of children P261: Avoid breathing dust/fume/gas/mist/vapours/spray P264: Wash thoroughly after handling P273: Avoid release to the environment P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician P501: Dispose of contents/container according to the separated collection system used in your municipality Precautionary statements: H302 - Harmful if swallowed H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H410 - Very toxic to aquatic life with long lasting effects Hazard statements: Danger CLP Regulation (EC) No 1272/2008: Page 1/13 Date of compilation: 16/02/2018 Version: 1 - CONTINUED ON NEXT PAGE -

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Page 1: SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND … … · Rampage Insecticide - Water dispersible granules (WG) Safety data sheet According to 1907/2006/EC (REACH), 2015/830/EU

Rampage

Insecticide - Water dispersible granules (WG)

Safety data sheet According to 1907/2006/EC (REACH), 2015/830/EU

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Local Poisons Information Centre Emergency telephone number: 1.4

Sapec Agro, S.A. Avenida do Rio Tejo, Herdade das Praias 2910-440 Setúbal - Setúbal - Portugal Phone.: +351265710100 - Fax: +351265710105 [email protected] www.sapecagro.pt

Details of the supplier of the safety data sheet: 1.3

Uses advised against: All uses not specified in this section or in section 7.3

Relevant uses: Fungicide for agricultural use. For professional user only.

Relevant identified uses of the substance or mixture and uses advised against: 1.2

Rampage Insecticide - Water dispersible granules (WG)

Product identifier: 1.1

SECTION 2: HAZARDS IDENTIFICATION

Label elements: 2.2

Acute Tox. 4: Acute toxicity if swallowed, Category 4, H302 Aquatic Acute 1: Hazardous to the aquatic environment, acute hazard, Category 1, H400 Aquatic Chronic 1: Hazardous to the aquatic environment, long-term hazard, Category 1, H410 Resp. Sens. 1: Sensitisation, respiratory, Category 1, H334

Classification of this product has been carried out in accordance with CLP Regulation (EC) No 1272/2008.

CLP Regulation (EC) No 1272/2008:

Classification of the substance or mixture: 2.1

Product fails to meet PBT/vPvB criteria

Other hazards: 2.3

Chlorpyrifos (ISO); 4,4´-methylenediphenyl diisocyanate, isomers and homologues

Substances that contribute to the classification

EUH204: Contains isocyanates. May produce an allergic reaction EUH208: Contains 2,2´-iminodi(ethylamine). May produce an allergic reaction EUH401: To avoid risks to human health and the environment, comply with the instructions for use SP1: Do not contaminate water with the product or its container

Supplementary information:

P101: If medical advice is needed, have product container or label at hand P102: Keep out of reach of children P261: Avoid breathing dust/fume/gas/mist/vapours/spray P264: Wash thoroughly after handling P273: Avoid release to the environment P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician P501: Dispose of contents/container according to the separated collection system used in your municipality

Precautionary statements:

H302 - Harmful if swallowed H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled

H410 - Very toxic to aquatic life with long lasting effects

Hazard statements:

Danger

CLP Regulation (EC) No 1272/2008:

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Page 2: SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND … … · Rampage Insecticide - Water dispersible granules (WG) Safety data sheet According to 1907/2006/EC (REACH), 2015/830/EU

Rampage

Insecticide - Water dispersible granules (WG)

Safety data sheet According to 1907/2006/EC (REACH), 2015/830/EU

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

In accordance with Annex II of Regulation (EC) No 1907/2006 (point 3), the product contains:

Components:

Organic compounds Chemical description:

Mixture: 3.2

Non-applicable

Substance: 3.1

Concentration Chemical name/Classification Identification

10 - <25 %

Acute Tox. 3: H301; Aquatic Acute 1: H400; Aquatic Chronic 1: H410 - Danger

Regulation 1272/2008

ATP CLP00 Chlorpyrifos (ISO) ¹

1 - <2,5 %

Aquatic Chronic 2: H411; Asp. Tox. 1: H304; EUH066 - Danger

Regulation 1272/2008

Self-classified Hydrocarbons, C10-C13, aromatics, < 1% naphthalene ¹

<1 %

Acute Tox. 4: H332; Carc. 2: H351; Eye Irrit. 2: H319; Resp. Sens. 1: H334; Skin Irrit. 2: H315; Skin Sens. 1: H317; STOT RE 2: H373; STOT SE 3: H335 - Danger

Regulation 1272/2008

ATP ATP01 4,4´-methylenediphenyl diisocyanate, isomers and homologues ¹

<1 %

Acute Tox. 2: H330; Acute Tox. 4: H302+H312; Eye Dam. 1: H318; Skin Corr. 1B: H314; Skin Sens. 1: H317; STOT SE 3: H335 - Danger

Regulation 1272/2008

Self-classified 2,2´-iminodi(ethylamine) ¹

¹ Substances presenting a health or environmental hazard which meet criteria laid down in Regulation (EU) No. 2015/830

Other information:

To obtain more information on the risk of the substances consult sections 8, 11, 12, 15 and 16.

M-factor Identification

10000 Chronic EC: 220-864-4 CAS: 2921-88-2

10000 Acute Chlorpyrifos (ISO)

Specific concentration limit Identification

% (w/w) >=5: Skin Irrit. 2 - H315 % (w/w) >=5: Eye Irrit. 2 - H319

% (w/w) >=0,1: Resp. Sens. 1 - H334 % (w/w) >=5: STOT SE 3 - H335

4,4´-methylenediphenyl diisocyanate, isomers and homologues CAS: 9016-87-9

EC: Non-applicable

(i) Substance considered registered under Article 15 (1) of Regulation 1907/2006; (ii) Substance considered as registered under Article 15 (2) of Regulation (EC) No 1907/2006; (iii) Substance exempted from registration under Article 2 (9) of Regulation 1907/2006; (iv) Substance exempt from registration under Article 2 (7) (a) of Regulation (EC) No 1907/2006; (v) Substance exempted from registration under Article 6 (1) of Regulation (EC) No 1907/2006; (vi) Substance exempted from registration under Article 2 (7) (b) of Regulation (EC) No 1907/2006; (vii) Substance exempted from registration under Article 2 (7) (c) of Regulation (EC) No 1907/2006

SECTION 4: FIRST AID MEASURES

By eye contact:

Remove contaminated clothing and footwear, rinse skin or shower the person affected if appropriate with plenty of cold water and neutral soap. In serious cases see a doctor. If the product causes burns or freezing, clothing should not be removed as this could worsen the injury caused if it is stuck to the skin. If blisters form on the skin, these should never be burst as this will increase the risk of infection.

By skin contact:

Remove the person affected from the area of exposure, provide with fresh air and keep at rest. In serious cases such as cardiorespiratory failure, artificial resuscitation techniques will be necessary (mouth to mouth resuscitation, cardiac massage, oxygen

supply, etc.) requiring immediate medical assistance.

By inhalation:

The symptoms resulting from intoxication can appear after exposure, therefore, in case of doubt, seek medical attention for direct exposure to the chemical product or persistent discomfort, showing the SDS of this product.

Description of first aid measures: 4.1

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2921-88-2

220-864-4 015-084-00-4

(i)

CAS:

EC: Index:

REACH:

64742-94-5

922-153-0 Non-applicable 01-2119451097-39-

XXXX

CAS:

EC: Index: REACH

: 9016-87-9

Non-applicable 615-005-00-9 Non data available

CAS:

EC: Index: REACH

: 111-40-0 203-865-4

612-058-00-X 01-2119473793-27-XXXX

CAS: EC:

Index: REACH:

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Rampage

Insecticide - Water dispersible granules (WG)

Safety data sheet According to 1907/2006/EC (REACH), 2015/830/EU

SECTION 4: FIRST AID MEASURES (continued)

Chlorpyrifos-ethyl is an acetyl cholinesterase inhibitor. Provide supportive care and symptomatic treatment. If swallowed induce vomiting or provide a gastric wash, avoiding aspiration; administrate activated charcoal or saline laxative (type: sodium or magnesium sulphate or similar). Control vital functions (respiratory, cardio and central nervous systems) and electrolytic equilibrium. Antidotes: atropine sulphate and oximes. Administrate atropine sulphate until symptoms of atropinization appears; provide blood analysis to check cholinesterase level, before administration of oxime (pralidoxime chloride or obidoxime chloride). Keep the treatment with oximes during the administration of atropine sulphate. In case of seizures administrate diazepam. At first signs of pulmonary oedema provide oxygen therapy e symptomatic treatment. Do not administrate morphine, aminophiline, anti histaminics, barbiturates, phenothiazines and other respiratory depressants, catecolamines, physostigmine, neostigmine or other anticholinesterase, fats including milk, and alcohol. Keep the patient under observation depending on the severity of poisoning, but

at least during 48 hours.

Indication of any immediate medical attention and special treatment needed: 4.3

(associated to active ingredients): (Chlorpyrifos-ethyl): Ingestion - gastrointestinal disorder: abdominal pain; nausea, vomiting, diarrhoea, weakness, behaviour disturbs as mental confusion, anxiety, emotional weakness, depression, irritability, vertigo, ataxia and coma in severe cases; fasciculations; convulsions; muscle paralysis, dyspnoea, cyanosis, myosis with blurred vision and watering of eyes, alteration of heart beat and blood pressure; deep sweating, sphincter incontinence. Inhalation – respiratory problems; cough, dyspnoea, increase in mucous secretions. Contact – Irritation of the eyes, skin and mucous; watering of eyes; rhinitis, contact

dermatitis, weak skin irritation and sensitization.

Acute and delayed effects are indicated in sections 2 and 11.

Most important symptoms and effects, both acute and delayed: 4.2

Request medical assistance immediately, showing the SDS of this product. Do not induce vomiting, but if it does happen keep the head down to avoid aspiration. In the case of loss of consciousness do not administer anything orally unless supervised by a doctor.

Rinse out the mouth and throat, as they may have been affected during ingestion. Keep the person affected at rest.

By ingestion/aspiration:

Rinse eyes thoroughly with water for at least 15 minutes. If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, in which case removal could cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as possible with the SDS for the product.

SECTION 5: FIREFIGHTING MEASURES

Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other emergencies. Eliminate all sources of ignition. In case of fire, cool the storage containers and tanks for products susceptible to combustion, explosion or BLEVE as a result of high temperatures. Avoid spillage of the products used to extinguish the fire into an aqueous medium.

Additional provisions:

Depending on the magnitude of the fire it may be necessary to use full protective clothing and self-contained breathing apparatus (SCBA). Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) in accordance with

Directive 89/654/EC.

Advice for firefighters: 5.3

As a result of combustion or thermal decomposition reactive sub-products are created that can become highly toxic and, consequently, can present a serious health risk.

Special hazards arising from the substance or mixture: 5.2

Product is non-flammable under normal conditions of storage, handling and use. In the case of combustion as a result of improper handling, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the Regulation on fire

protection systems. IT IS NOT RECOMMENDED to use tap water as an extinguishing agent.

Extinguishing media: 5.1

SECTION 6: ACCIDENTAL RELEASE MEASURES

Sweep up and shovel product or collect by other means and place in container for reuse (preferred) or disposal

It is recommended:

Methods and material for containment and cleaning up: 6.3

Avoid at all cost any type of spillage into an aqueous medium. Contain the product absorbed appropriately in hermetically sealed containers. Notify the relevant authority in case of exposure to the general public or the environment.

Environmental precautions: 6.2

Sweep up and shovel product or collect by other means and place in container for reuse (preferred) or disposal

Personal precautions, protective equipment and emergency procedures: 6.1

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Rampage

Insecticide - Water dispersible granules (WG)

Safety data sheet According to 1907/2006/EC (REACH), 2015/830/EU

SECTION 6: ACCIDENTAL RELEASE MEASURES (continued)

See sections 8 and 13.

Reference to other sections: 6.4

SECTION 7: HANDLING AND STORAGE

24 Months Maximum time:

Technical measures for storage A.-

Conditions for safe storage, including any incompatibilities: 7.2

Sweep up and shovel product or collect by other means and place in container for reuse (preferred) or disposal See sections 8 and 13.

Technical recommendations to prevent environmental risks D.-

Do not eat or drink during the process, washing hands afterwards with suitable cleaning products.

Technical recommendations to prevent ergonomic and toxicological risks C.-

Due to its non-flammable nature, the product does not present a fire risk under normal conditions of storage, handling and use.

Technical recommendations for the prevention of fires and explosions B.-

Comply with the current legislation concerning the prevention of industrial risks. Keep containers hermetically sealed. Control spills and residues, destroying them with safe methods (section 6). Avoid leakages from the container. Maintain order and cleanliness

where dangerous products are used.

Precautions for safe manipulation A.-

Precautions for safe handling: 7.1

Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this product.

Specific end use(s): 7.3

Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5

General conditions for storage B.-

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Substances whose occupational exposure limits have to be monitored in the work environment

Control parameters: 8.1

DNEL (Workers):

Nuisance dust: Inhalable dust 10 mg/m3 // Respirable dust 4 mg/m3

Local Systemic Local Systemic Identification

Long exposure Short exposure

Non-applicable 151 mg/m³ Non-applicable Non-applicable Inhalation EC: 922-153-0

Non-applicable 12,5 mg/kg Non-applicable Non-applicable Dermal CAS: 64742-94-5

Non-applicable Non-applicable Non-applicable Non-applicable Oral Hydrocarbons, C10-C13, aromatics, < 1% naphthalene

0,87 mg/m³ 15,4 mg/m³ 2,6 mg/m³ 92,1 mg/m³ Inhalation EC: 203-865-4

Non-applicable 11,4 mg/kg Non-applicable Non-applicable Dermal CAS: 111-40-0

Non-applicable Non-applicable Non-applicable Non-applicable Oral 2,2´-iminodi(ethylamine)

DNEL (General population):

Local Systemic Local Systemic Identification

Long exposure Short exposure

Non-applicable 32 mg/m³ Non-applicable Non-applicable Inhalation EC: 922-153-0

Non-applicable 7,5 mg/kg Non-applicable Non-applicable Dermal CAS: 64742-94-5

Non-applicable 7,5 mg/kg Non-applicable Non-applicable Oral Hydrocarbons, C10-C13, aromatics, < 1% naphthalene

Non-applicable 4,6 mg/m³ Non-applicable 27,5 mg/m³ Inhalation EC: 203-865-4

Non-applicable 4,88 mg/kg Non-applicable 4,88 mg/kg Dermal CAS: 111-40-0

Non-applicable Non-applicable Non-applicable Non-applicable Oral 2,2´-iminodi(ethylamine)

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Rampage

Insecticide - Water dispersible granules (WG)

Safety data sheet According to 1907/2006/EC (REACH), 2015/830/EU

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continued)

PNEC:

Identification

107,2 mg/kg Sediment (Marine water) Non-applicable Oral

1072 mg/kg Sediment (Fresh water) 0,32 mg/L Intermittent EC: 203-865-4

0,056 mg/L Marine water 214 mg/kg Soil CAS: 111-40-0

0,56 mg/L Fresh water 6 mg/L STP 2,2´-iminodi(ethylamine)

Respiratory protection B.-

As a preventative measure it is recommended to use basic Personal Protective Equipment, with the corresponding <<CE marking>> in accordance with Directive 89/686/EC. For more information on Personal Protective Equipment (storage, use, cleaning, maintenance, class of protection,…) consult the information leaflet provided by the manufacturer. For more information see subsection 7.1. All information contained herein is a recommendation which needs some specification from the labour risk prevention services as it is not known whether the company has additional measures at its disposal.

General security and hygiene measures in the work place A.-

Exposure controls: 8.2

Remarks CEN Standard Labelling PPE Pictogram

Replace when an increase in resistence to breathing is observed and/or a smell or taste of the

contaminant is detected.

EN 149:2001+A1:2009 EN 405:2001+A1:2009

Filter mask for gases, vapours and particles

Mandatory respiratory tract

protection

Specific protection for the hands C.-

Remarks CEN Standard Labelling PPE Pictogram

Replace gloves in case of any sign of damage. For prolonged periods of exposure to the product for

professional users/industrials, we recommend using CE III gloves in line with standards EN 420 and EN

374.

Protective gloves against minor risks

Mandatory hand protection

Ocular and facial protection D.-

"As the product is a mixture of several substances, the resistance of the glove material can not be predicted in advance with total reliability and has therefore to be checked prior to the application"

Remarks CEN Standard Labelling PPE Pictogram

Clean daily and disinfect periodically according to the manufacturer´s instructions. Use if there is a

risk of splashing.

EN 166:2001 EN ISO 4007:2012

Panoramic glasses against splash/projections.

Mandatory face protection

Body protection E.-

Remarks CEN Standard Labelling PPE Pictogram

Replace before any evidence of deterioration. For periods of prolonged exposure to the product for

professional/industrial users CE III is recommended, in accordance with the regulations in EN ISO

6529:2001, EN ISO 6530:2005, EN ISO 13688:2013, EN 464:1994.

Work clothing

Replace before any evidence of deterioration. For periods of prolonged exposure to the product for

professional/industrial users CE III is recommended, in accordance with the regulations in EN ISO 20345

y EN 13832-1

EN ISO 20347:2012

Anti-slip work shoes

Additional emergency measures F.-

Standards Emergency measure Standards Emergency measure

DIN 12 899 ISO 3864-1:2002

Eyewash stations

ANSI Z358-1 ISO 3864-1:2002

Emergency shower

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Rampage

Insecticide - Water dispersible granules (WG)

Safety data sheet According to 1907/2006/EC (REACH), 2015/830/EU

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continued)

103,2 g/mol Average molecular weight:

4 Average carbon number:

Non-applicable V.O.C. density at 20 ºC:

0,17 % weight V.O.C. (Supply):

With regard to Directive 2010/75/EU, this product has the following characteristics:

Volatile organic compounds:

In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental spillage

of both the product and its container. For additional information see subsection 7.1.D

Environmental exposure controls:

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Non-applicable * Lower flammability limit:

Non-applicable * Autoignition temperature:

Non-applicable * Flammability (solid, gas):

Non-applicable Flash Point:

Flammability:

Non-applicable * Oxidising properties:

Non-applicable * Explosive properties:

Non-applicable * Melting point/freezing point:

Non-applicable * Decomposition temperature:

Non-applicable * Solubility properties:

Non-applicable * Solubility in water at 20 ºC:

Non-applicable * Partition coefficient n-octanol/water 20 ºC:

Non-applicable * Vapour density at 20 ºC:

Non-applicable * pH:

Non-applicable * Concentration:

Non-applicable * Kinematic viscosity at 40 ºC:

Non-applicable * Kinematic viscosity at 20 ºC:

Non-applicable * Dynamic viscosity at 20 ºC:

Non-applicable * Relative density at 20 ºC:

Non-applicable * Density at 20 ºC:

Product description:

Non-applicable * Evaporation rate at 20 ºC:

<300000 Pa (300 kPa) Vapour pressure at 50 ºC:

Non-applicable * Vapour pressure at 20 ºC:

Non-applicable * Boiling point at atmospheric pressure:

Volatility:

Non-applicable * Odour threshold:

Not available Odour:

Not available Colour:

Granulated Appearance:

Solid Physical state at 20 ºC:

Appearance:

For complete information see the product datasheet.

Information on basic physical and chemical properties: 9.1

*Not relevant due to the nature of the product, not providing information property of its hazards.

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Rampage

Insecticide - Water dispersible granules (WG)

Safety data sheet According to 1907/2006/EC (REACH), 2015/830/EU

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continued)

Non-applicable * Refraction index:

Non-applicable * Surface tension at 20 ºC:

Other information: 9.2

Non-applicable * Upper explosive limit:

Non-applicable * Lower explosive limit:

Explosive:

Non-applicable * Upper flammability limit:

*Not relevant due to the nature of the product, not providing information property of its hazards.

SECTION 10: STABILITY AND REACTIVITY

See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions, complex mixtures of chemical substances can be released: carbon dioxide (CO2), carbon monoxide and other organic compounds.

Hazardous decomposition products: 10.6

Avoid alkalis or strong bases Not applicable Avoid direct impact Not applicable Avoid strong acids

Others Combustible materials Combustive materials Water Acids

Incompatible materials: 10.5

Not applicable Not applicable Not applicable Not applicable Not applicable

Humidity Sunlight Increase in temperature Contact with air Shock and friction

Applicable for handling and storage at room temperature:

Conditions to avoid: 10.4

Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected.

Possibility of hazardous reactions: 10.3

Chemically stable under the conditions of storage, handling and use.

Chemical stability: 10.2

No hazardous reactions are expected because the product is stable under recommended storage conditions. See section 7.

Reactivity: 10.1

SECTION 11: TOXICOLOGICAL INFORMATION

- Contact with the skin: Based on available data, the classification criteria are not met. However, it contains substances classified as dangerous for skin contact. For more information see section 3. - Contact with the eyes: Based on available data, the classification criteria are not met. However, it does contain substances classified as dangerous for this effect. For more information see section 3.

Contact with the skin and the eyes (acute effect): C-

- Acute toxicity : Based on available data, the classification criteria are not met. However, it contains substances classified as dangerous for inhalation. For more information see section 3. - Corrosivity/Irritability: Based on available data, the classification criteria are not met. However, it does contain substances classified as dangerous for this effect. For more information see section 3.

Inhalation (acute effect): B-

- Acute toxicity : The consumption of a considerable dose can cause irritation in the throat, abdominal pain, nausea and vomiting. - Corrosivity/Irritability: Based on available data, the classification criteria are not met. However, it does contain substances

classified as dangerous for this effect. For more information see section 3.

Ingestion (acute effect): A.-

In case of exposure that is repetitive, prolonged or at concentrations higher than the recommended occupational exposure limits, adverse effects on health may result, depending on the means of exposure:

Dangerous health implications:

Information on toxicological effects: 11.1

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Rampage

Insecticide - Water dispersible granules (WG)

Safety data sheet According to 1907/2006/EC (REACH), 2015/830/EU

SECTION 11: TOXICOLOGICAL INFORMATION (continued)

Specific toxicology information on the substances:

Acute Effects (Chlorpyrifos-ethyl): Skin corrosion/ irritation: Mildly irritating Serious eye damage/irritation: Mildly irritating Respiratory sensitisation: No information available Skin sensitisation: Not a skin sensitizer (Guinea pigs) Chronic effects (Chlorpyrifos-ethyl): Mutagenicity: Not observed Carcinogenicity: Not observed Reproductive toxicity: Not observed STOT- single exposure: Not demonstrated STOT- repeated exposure: Not demonstrated Aspiration hazard: No information available (*) Based on available data, the classification criteria are not met.

Other information:

Based on available data, the classification criteria are not met. However, it does contain substances classified as dangerous for this effect. For more information see section 3.

Aspiration hazard: H-

- Specific target organ toxicity (STOT)-repeated exposure: Based on available data, the classification criteria are not met. However, it does contain substances which are classified as dangerous due to repetitive exposure. For more information see section 3. - Skin: Remove contaminated clothing and footwear, rinse skin or shower the person affected if appropriate with plenty of cold water and neutral soap. In serious cases see a doctor. If the product causes burns or freezing, clothing should not be removed as this could worsen the injury caused if it is stuck to the skin. If blisters form on the skin, these should never be burst as this will increase the risk of infection.

Specific target organ toxicity (STOT)-repeated exposure: G-

Based on available data, the classification criteria are not met. However, it contains substances classified as dangerous for inhalation. For more information see section 3.

Specific target organ toxicity (STOT) - single exposure: F-

- Respiratory: Prolonged exposure can result in specific respiratory hypersensitivity. - Cutaneous: Based on available data, the classification criteria are not met. However, it contains substances classified as

dangerous with sensitising effects. For more information see section 3.

Sensitizing effects: E-

- Carcinogenicity: Based on available data, the classification criteria are not met. However, it contains substances classified as dangerous with carcinogenic effects. For more information see section 3. - Mutagenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. - Reproductive toxicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3.

CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction): D-

Genus Acute toxicity Identification

>20 mg/L (4 h) LC50 inhalation EC: 922-153-0

>2000 mg/kg LD50 dermal CAS: 64742-94-5

Rat 10650 mg/kg LD50 oral Hydrocarbons, C10-C13, aromatics, < 1% naphthalene

Rat >1 mg/L (4 h) LC50 inhalation EC: 220-864-4

Rat >4000 mg/kg LD50 dermal CAS: 2921-88-2

Rat 276 mg/kg LD50 oral Chlorpyrifos (ISO)

0,05 mg/L (4 h) (ATEi) LC50 inhalation EC: 203-865-4

Rabbit 1045 mg/kg (ATEi) LD50 dermal CAS: 111-40-0

Rat 1620 mg/kg LD50 oral 2,2´-iminodi(ethylamine)

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Insecticide - Water dispersible granules (WG)

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SECTION 11: TOXICOLOGICAL INFORMATION (continued)

Genus Acute toxicity Identification

>20 mg/L LC50 inhalation EC: Non-applicable

>2000 mg/kg LD50 dermal CAS: 9016-87-9

>2000 mg/kg LD50 oral 4,4´-methylenediphenyl diisocyanate, isomers and homologues

0 % 29,82 mg/L (4 h) (Calculation method) Inhalation

Non-applicable >2000 mg/kg (Calculation method) Dermal

0 % 1540,18 mg/kg (Calculation method) Oral

Ingredient(s) of unknown toxicity ATE mix

Acute Toxicity Estimate (ATE mix):

SECTION 12: ECOLOGICAL INFORMATION

Toxicity: 12.1

Genus Species Acute toxicity Identification

Algae Scenedesmus subspicatus 0.48 mg/l (72h) EC50 EC: 220-864-4

Crustacean Daphnia magna 1.7 μg//L (48 h) EC50 CAS: 2921-88-2

Fish Rainbow trout 3 μg/l (96h) LC50 Chlorpyrifos (ISO)

Algae 1 - 10 mg/L EC50 EC: 922-153-0

Crustacean 1 - 10 mg/L EC50 CAS: 64742-94-5

Fish 1 - 10 mg/L (96 h) LC50 Hydrocarbons, C10-C13, aromatics, < 1% naphthalene

Algae Selenastrum capricornutum 187 mg/L (72 h) EC50 EC: 203-865-4

Crustacean Daphnia magna 16 mg/L (48 h) EC50 CAS: 111-40-0

Fish Poecilia reticulada 430 mg/L (96 h) LC50 2,2´-iminodi(ethylamine)

Persistence and degradability: 12.2

Acute toxicity (Chlorpyrifos-ethyl): Birds acute Oral LD50: 13.3 mg/kg (Bobwhite quail); 75.6 mg/kg (Mallard ducks) Bee oral LD50: 0.36 μg/bee Bee contact LD50: 0.070 μg/bee Aquatic plants CE50 (7 d): NA Chronic toxicity (Chlorpyrifos-ethyl): Fish chronic NOEC (90 d): 1.8 μg/l (Rainbow trout) Aquatic invertebrates chronic NOEC (21 d): 0.056 mg/l (Daphnia magna)

Algae chronic NOEC: 0.1-0.001 mg/l

Biodegradability Degradability Identification

70 % % Biodegradable Non-applicable BOD5/COD EC: 922-153-0

28 days Period Non-applicable COD CAS: 64742-94-5

Non-applicable Concentration Non-applicable BOD5 Hydrocarbons, C10-C13, aromatics, < 1% naphthalene

87 % % Biodegradable Non-applicable BOD5/COD EC: 203-865-4

21 days Period Non-applicable COD CAS: 111-40-0

10 mg/L Concentration Non-applicable BOD5 2,2´-iminodi(ethylamine)

Bioaccumulative potential: 12.3

- Chlorpyrifos-ethyl (Soil): Moderately persistent in soil. Typical DT50: 50 d; Lab DT50: 76 d; Field DT50: 21 d. - Water: Moderately fast chemical degradation in water-sediment systems, DT50: 36,5 d. Moderately fast chemical degradation in water phase only, DT50: 5 d. Chlorpyrifos-ethylis biodegradable.

Bioaccumulation potential Identification

Very High Potential EC: 220-864-4

4.96 Pow Log CAS: 2921-88-2

4667 BCF Chlorpyrifos (ISO)

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Insecticide - Water dispersible granules (WG)

Safety data sheet According to 1907/2006/EC (REACH), 2015/830/EU

SECTION 12: ECOLOGICAL INFORMATION (continued)

Bioaccumulation potential Identification

Low Potential EC: 203-865-4

-1.3 Pow Log CAS: 111-40-0

2 BCF 2,2´-iminodi(ethylamine)

Mobility in soil: 12.4

(Chlorpyrifos-ethyl): Moderate bioaccumulation potential. Log Pow= 4.7. BCF: 1374.

Volatility Absorption/desorption Identification

Yes Moist soil Non-applicable Surface tension EC: 220-864-4

No Dry soil Conclusion CAS: 2921-88-2

2,938E-1 Pa·m³/mol Henry 6070 Koc Chlorpyrifos (ISO)

Non-applicable Moist soil 4,164E-2 N/m (25 ºC) Surface tension EC: 203-865-4

Non-applicable Dry soil Non-applicable Conclusion CAS: 111-40-0

Non-applicable Henry Non-applicable Koc 2,2´-iminodi(ethylamine)

Not described

Other adverse effects: 12.6

Product fails to meet PBT/vPvB criteria

Results of PBT and vPvB assessment: 12.5

(Chlorpyrifos-ethyl): Not mobile in the environment, but is strongly adsorbed to soil.

SECTION 13: DISPOSAL CONSIDERATIONS

Community legislation: Directive 2008/98/EC, 2014/955/EU, Regulation (EU) No 1357/2014

In accordance with Annex II of Regulation (EC) No 1907/2006 (REACH) the community or state provisions related to waste management are stated

Regulations related to waste management:

Consult the authorized waste service manager on the assessment and disposal operations in accordance with Annex 1 and Annex 2 (Directive 2008/98/EC). As under 15 01 (2014/955/EC) of the code and in case the container has been in direct contact with the product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-dangerous residue. We do

not recommended disposal down the drain. See paragraph 6.2.

Waste management (disposal and evaluation):

HP14 Ecotoxic, HP6 Acute Toxicity

Type of waste (Regulation (EU) No 1357/2014):

Dangerous agrochemical waste containing hazardous substances 02 01 08*

Waste class (Regulation (EU) No 1357/2014)

Description Code

Waste treatment methods: 13.1

SECTION 14: TRANSPORT INFORMATION

With regard to ADR 2017 and RID 2017:

Transport of dangerous goods by land:

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Insecticide - Water dispersible granules (WG)

Safety data sheet According to 1907/2006/EC (REACH), 2015/830/EU

SECTION 14: TRANSPORT INFORMATION (continued)

Transport in bulk according to Annex II of Marpol and the

IBC Code:

Non-applicable 14.7

Special precautions for user

Environmental hazards: Yes 14.5

Non-applicable Tunnel restriction code:

14.6

14.4

14.3

14.2

14.1

Labels:

UN proper shipping name:

Packing group:

Transport hazard class(es):

UN number:

Special regulations:

Physico-Chemical properties:

UN3077

9

III

9

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Hydrocarbons, C10-C13, aromatics, < 1% naphthalene; Chlorpyrifos (ISO))

274, 335, 375, 601

see section 9

Limited quantities: 5 kg

With regard to IMDG 38-16:

Transport of dangerous goods by sea:

Transport in bulk according to Annex II of Marpol and the

IBC Code:

Non-applicable 14.7

Special precautions for user

Environmental hazards: Yes 14.5

F-A, S-F EmS Codes:

14.6

14.4

14.3

14.2

14.1

Labels:

UN proper shipping name:

Packing group:

Transport hazard class(es):

UN number:

Special regulations:

Physico-Chemical properties:

UN3077

9

III

9

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Hydrocarbons, C10-C13, aromatics, < 1% naphthalene; Chlorpyrifos (ISO))

335, 966, 274, 967, 969

see section 9

Limited quantities: 5 kg

With regard to IATA/ICAO 2017:

Transport of dangerous goods by air:

14.6

14.4

14.3

14.2

14.1

see section 9 Physico-Chemical properties:

III Packing group:

9 Labels:

9 Transport hazard class(es):

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Hydrocarbons, C10-C13, aromatics, < 1% naphthalene; Chlorpyrifos

(ISO))

UN proper shipping name:

UN number: UN3077

Environmental hazards: Yes 14.5

Transport in bulk according to Annex II of Marpol and the

IBC Code:

Non-applicable 14.7

Special precautions for user

SECTION 15: REGULATORY INFORMATION

Regulation (EC) No 528/2012: contains a preservative to protect the initial properties of the treated article. Contains 1,2-benzisothiazol-3(2H)-one.

Safety, health and environmental regulations/legislation specific for the substance or mixture: 15.1

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Insecticide - Water dispersible granules (WG)

Safety data sheet According to 1907/2006/EC (REACH), 2015/830/EU

SECTION 15: REGULATORY INFORMATION (continued)

REGULATION (EU) No 649/2012, in relation to the import and export of hazardous chemical products: Non-applicable

Article 95, REGULATION (EU) No 528/2012: Non-applicable

Regulation (EC) No 1005/2009, about substances that deplete the ozone layer: Non-applicable

Substances included in Annex XIV of REACH ("Authorisation List") and sunset date: Non-applicable

Candidate substances for authorisation under the Regulation (EC) No 1907/2006 (REACH): Non-applicable

The supplier has not carried out evaluation of chemical safety.

Chemical safety assessment: 15.2

Seveso III Category: E1

Other information:

Regulation (EU) No 528/2012 of the European Parliament and of the Council of 22 May 2012 concerning the making available on the market and use of biocidal products

The product could be affected by sectorial legislation

Other legislation:

It is recommended to use the information included in this safety data sheet as a basis for conducting workplace-specific risk

assessments in order to establish the necessary risk prevention measures for the handling, use, storage and disposal of this product.

Specific provisions in terms of protecting people or the environment:

Contains more than 0.1 % of 4,4´-methylenediphenyl diisocyanate, isomers and homologues by weight. This product may not be distributed in its present form for first-time sale to the general public after 27th December 2010 unless the packaging contains protective gloves meeting the provisions of European Council Directive 89/686/CEE.

Limitations to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII REACH, etc ….):

SECTION 16: OTHER INFORMATION

Classification procedure:

Acute Tox. 2: H330 - Fatal if inhaled Acute Tox. 3: H301 - Toxic if swallowed Acute Tox. 4: H302+H312 - Harmful if swallowed or in contact with skin Acute Tox. 4: H332 - Harmful if inhaled Aquatic Acute 1: H400 - Very toxic to aquatic life Aquatic Chronic 1: H410 - Very toxic to aquatic life with long lasting effects Aquatic Chronic 2: H411 - Toxic to aquatic life with long lasting effects Asp. Tox. 1: H304 - May be fatal if swallowed and enters airways Carc. 2: H351 - Suspected of causing cancer Eye Dam. 1: H318 - Causes serious eye damage Eye Irrit. 2: H319 - Causes serious eye irritation Resp. Sens. 1: H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled Skin Corr. 1B: H314 - Causes severe skin burns and eye damage Skin Irrit. 2: H315 - Causes skin irritation Skin Sens. 1: H317 - May cause an allergic skin reaction STOT RE 2: H373 - May cause damage to organs through prolonged or repeated exposure STOT SE 3: H335 - May cause respiratory irritation

CLP Regulation (EC) No 1272/2008:

The phrases indicated do not refer to the product itself; they are present merely for informative purposes and refer to the individual components which appear in section 3

Texts of the legislative phrases mentioned in section 3:

H410: Very toxic to aquatic life with long lasting effects H400: Very toxic to aquatic life H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled H302: Harmful if swallowed

Texts of the legislative phrases mentioned in section 2:

Non-applicable

Modifications related to the previous Safety Data Sheet which concerns the ways of managing risks.:

This safety data sheet has been designed in accordance with ANNEX II-Guide to the compilation of safety data sheets of Regulation

(EC) No 1907/2006 (Regulation (EC) No 2015/830)

Legislation related to safety data sheets:

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Insecticide - Water dispersible granules (WG)

Safety data sheet According to 1907/2006/EC (REACH), 2015/830/EU

SECTION 16: OTHER INFORMATION (continued)

Content review: The sections / sub sections marked with () were changed with relevant information, from the previous version.

Cod.: PF-946-C

Other information:

ADR: European agreement concerning the international carriage of dangerous goods by road IMDG: International maritime dangerous goods code IATA: International Air Transport Association ICAO: International Civil Aviation Organisation COD: Chemical Oxygen Demand BOD5: 5-day biochemical oxygen demand BCF: Bioconcentration factor LD50: Lethal Dose 50 LC50: Lethal Concentration 50 EC50: Effective concentration 50 Log-POW: Octanol–water partition coefficient Koc: Partition coefficient of organic carbon

Abbreviations and acronyms:

http://echa.europa.eu

http://eur-lex.europa.eu

Principal bibliographical sources:

Minimal training is recommended in order to prevent industrial risks for staff using this product and to facilitate their comprehension

and interpretation of this safety data sheet, as well as the label on the product.

Advice related to training:

Aquatic Chronic 1: Calculation method Aquatic Acute 1: Calculation method Resp. Sens. 1: Calculation method

Acute Tox. 4: Calculation method

The information contained in this safety data sheet is based on sources, technical knowledge and current legislation at European and state level, without being able to guarantee its accuracy.

This information cannot be considered a guarantee of the properties of the product, it is simply a description of the security requirements. The occupational methodology and conditions for users

of this product are not within our awareness or control, and it is ultimately the responsibility of the user to take the necessary measures to obtain the legal requirements concerning the manipulation, storage, use and disposal of chemical products. The information on this safety data sheet only refers to this product, which should not be used for needs other than those specified.

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