~-mcte-2-~-2'-1-m ~. ~~m~ - niscairnopr.niscair.res.in/bitstream/123456789/3173/1/bvaap 15(2)...

4
1iffifm ~ ~ ~ J$tJR qf:m- eN 15 Jtcn 2 ~ 2007 ~. 137-140 ~-mcte-2-~-2"'-1-m ~. ~ -«~~t4\JlI~ctl ~ m~t4\JlI~ctl ~ ~~~~~ ~~m~ ~ ~llTI fcr1:rrT, ~ fcr~cjRl~I<:1<j, ~ - 211 002 mU~T : ~ ~n-q q::r if ~-;:rrq:c -2- l!.>hI~<:1l!.l.JI~il-2- ~ -)- IDi'R ~\"-hIMCh ~ CfiT "B'~~ ~T7111 TjT;IT ~ 0m ~ 1fRl ~ oF rn B~ T1Tm if fcRTI 1fI1T % I~ \R fc!ftFr ~ ctr ~ oFm CfiT \31[lfi:R m fcRTI 1fI1T 0ffi C[T7:[T 1fI1T fct ~ -2- l!.>h1~<:1l!.l.J1~51 -2- ~ -1- IDi'R ~~IMCh ~ 0ffi ~ ctr ~ ~ \R ~ ~ m~ % I~ oF 0ITtm \R C[T7:[T 1fI1T fct 40°C GN \R ~ ff \R ~ qfturrJ:r ~ ~ I "B'~~ ;:rrq:c il ,!'rIM l.J <. CfiT fcr~~ ~ ~ ct<1«hI YI 0ffi GN ~ fcr~~ ImT fcRTI 1fI1T % I Dextron-graft-2-achrylamydo-2-methyI-l-propane sulphonic acid : Synthetical & analytical study Abhishek Srivastava & Kunj Bihari Polymer Science Research Laboratory Department of Chemistry, Allahabad University, Allahabad - 211 002 Abstract In the present study dextron-graft-2-achrylamydo-2-methyl-l-propane sulphonic acid was synthesized by radicals free fram potassium mono persulphate and thiourea in inactive medium. In this the study ofthe effect of concentration of different reactants on the reactions was also carried out. Results revealed that on increasing the concentration ofthiourea -2- achrylamido -2- methyl- 1- propane suiphonic acid and dextran grafting parameter also increased. It was also determined that better results are obtained when the reaction occurs on 40°C temperature. Analysis of synthesised graft copolymer was done by spectroscopy and tempera- ture quantitative anylysis. lolttllCl11 ~ RJ~«-il ~ if ~ ~ ~ 'f\ rcr~Tcr t.ITR m \ilT WT %' \3tR RJ ~«-i l~ ~ ~ fuo; WQfd if 1:1Tir \JfR emir ~ cR m \3m- '4t \JfrtT %,1,2 I~ ~ ~ 0fu:?j!$ ~ %' I~ '*r ~ 0fu: '*r Hkj"Ie{)~\J1 ~ ~ CfiT\DT ~ cm% ~ fctm ~ tl ~ " ",. ~ ~ ~ cITW?, ~ ~, ~, m i3tirr, e{)1~ Ice{) iJtiM if ~ ~ ~ if \31cf.'r ~ ~11 M e{) ~ if cruHfcFJm t~ ~ cm% ~ CDT c::~1fcrr %' I~ ~~ cm%:rIT ~ 0mT ~ cgt9 ~ (~fCF ~~ ~ ~ ~ '@R;r~furrill) '4t 1Wfr \Jffifr ~ ~ ~ ~ CDT cgt9 rcr~Tcrqfifu \lcD ~ em ~ t I~ \31cfTIT CDT ~ ~ ~ fuo; ~ mQ cR ~1~1<1f:ie{) ~ ~ \iffitt ~ ~ ~~ chIYl81~~I~~~H fc1fu wffi ~ ~ ~t I~ ~TIt:r-tR if W mfu cnr ~ fctm Tr:rf %' I

Upload: others

Post on 23-Mar-2020

2 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: ~-mcte-2-~-2'-1-m ~. ~~m~ - NISCAIRnopr.niscair.res.in/bitstream/123456789/3173/1/BVAAP 15(2) 137-140.pdf · 138 2- lI,~I\'I~\'IlI,l-jI~SI -2-m-1-00 ~~IHcn ~-ij~ :sit~ em CIfT1Tc{)

1iffifm ~ ~ ~ J$tJR qf:m­

eN 15 Jtcn 2 ~ 2007 ~. 137-140

~-mcte-2-~-2"'-1-m ~.

~ -«~~t4\JlI~ctl ~ m~t4\JlI~ctl ~

~~~~~

~~m~~ ~llTI fcr1:rrT, ~ fcr~cjRl~I<:1<j, ~ - 211 002

mU~T : ~ ~n-qq::r if ~-;:rrq:c -2- l!.>hI~<:1l!.l.JI~il-2- ~ -)- IDi'R ~\"-hIMCh ~ CfiT "B'~~ ~T7111 TjT;IT ~

0m ~ 1fRl ~ oFrn B ~ T1Tm if fcRTI 1fI1T % I ~ \R fc!ftFr ~ ctr ~ oFm CfiT \31[lfi:R

m fcRTI 1fI1T 0ffi C[T7:[T1fI1T fct ~ -2- l!.>h1~<:1l!.l.J1~51-2- ~ -1- IDi'R ~~IMCh ~ 0ffi ~ ctr ~ ~ \R

~ ~ m ~ % I ~ oF 0ITtm \R C[T7:[T1fI1T fct 40°C GN \R ~ ff \R ~ qfturrJ:r ~ ~ I "B'~~ ;:rrq:c

il ,!'rIM l.J<. CfiT fcr~~ ~ ~ ct<1«hI YI 0ffi GN ~ fcr~~ ImT fcRTI 1fI1T % I

Dextron-graft-2-achrylamydo-2-methyI-l-propane sulphonic acid :Synthetical & analytical study

Abhishek Srivastava & Kunj BihariPolymer Science Research Laboratory

Department of Chemistry, Allahabad University, Allahabad - 211 002

Abstract

In the present study dextron-graft-2-achrylamydo-2-methyl-l-propane sulphonic acid was synthesized by radicals free frampotassium mono persulphate and thiourea in inactive medium. In this the study ofthe effect of concentration of different reactantson the reactions was also carried out. Results revealed that on increasing the concentration ofthiourea -2- achrylamido -2- methyl­1- propane suiphonic acid and dextran grafting parameter also increased. It was also determined that better results are obtainedwhen the reaction occurs on 40°C temperature. Analysis of synthesised graft copolymer was done by spectroscopy and tempera­ture quantitative anylysis.

lolttllCl11

~ RJ~«-il ~ if ~ ~ ~ 'f\ rcr~Tcr

t.ITR m \ilT WT %' \3tR RJ~«-il~ ~ ~ fuo; WQfd if 1:1Tir

\JfR emir ~ cR m \3m- '4t \JfrtT %,1,2 I ~ ~

~ 0fu:?j!$ ~ %' I ~ '*r ~ 0fu: '*r Hkj"Ie{)~\J1

~ ~ CfiT\DT ~ cm% ~ fctm ~ tl ~

" ",. ~ ~ ~ cITW?, ~ ~, ~, mi3tirr, e{)1~ Ice{) iJtiM if ~ ~ ~ if \31cf.'r ~ ~11Me{) ~

if cruHfcFJmt~ ~ cm% ~ CDTc::~1fcrr %' I ~

~ ~ cm%:rIT ~ 0mT ~ cgt9 ~ (~fCF ~~

~ ~ ~ '@R;r~furrill) '4t 1Wfr \Jffifr ~ ~ ~

~ CDTcgt9 rcr~Tcrqfifu \lcD ~ em ~ t I ~ \31cfTIT

CDT ~ ~ ~ fuo; ~ mQ cR ~1~1<1f:ie{) ~ ~

\iffitt ~ ~ ~ ~ chIYl81~~I~~~Hfc1fuwffi ~ ~~ t I ~ ~TIt:r-tR if W mfu cnr ~ fctm Tr:rf %' I

Page 2: ~-mcte-2-~-2'-1-m ~. ~~m~ - NISCAIRnopr.niscair.res.in/bitstream/123456789/3173/1/BVAAP 15(2) 137-140.pdf · 138 2- lI,~I\'I~\'IlI,l-jI~SI -2-m-1-00 ~~IHcn ~-ij~ :sit~ em CIfT1Tc{)

138

2- lI,~I\'I~\'IlI,l-jI~SI -2- m -1- 00 ~~IHcn ~-ij

~ :sit~ em CIfT1Tc{) rn ~ ~ITtR~8 \3fR fcrfiF1

>mm ct @rW CAR if fcmr ~ ~ I ~ ~iTqq;r if ~

2-1J,~1\'I~\'I1J,1l1~il-2- ~ -1- ffi ~~IHctJ ~ctw~~- meR -2-1J,~1~\'I1J,1l1~il-2-m-1- ~ ~~IHctJ

~ em ~~~ cnR em m fcRrr lTm & I

~lWl1fRt 4(tl~t it ~ CfiT ~ : ~ 1:R

~ lfRT y" l;10-hc eft ~ cj) m em 01v:r:H fcnm

'l<:fT 0fR qr:rr 'l<:fT fc1:l ~ ~ Y( ~ 0-hC ctr ~

14 x 10-3 mol dm-3 (fCF) qq;Rq{ 'JTNtrT ~ ~ 01f.l,

r ~ ~ ~ ~ JfR 01fucn qq;Rq{ ~ ~ em

11R IlCill ~ & I

~ 1- ~ 1f8T ~ CJit mtill 'fiTm(~1f8T~) %G %A %C

x ]0' mol dm-'

~'~I,!R~1tT mrn ctT JrlTICf : 2.j1~~I4P~1tr ~ q:;r

~ 1:R ~ ~ >fl1TCf em \31v:r:R fc8Tr 'l<:fT 0fR qr:rr 'l<:fT

fc1:l ~~121~~S~1~)I<iR~1~ JfR ~ ~ Y(~0-h( ctr

~ ~ ~ m~ ~ ~ eft q)11 ~t:fill cj)

c.nr:oT ~1~~lqF~1eft ~ ~ ~ ~ q"I.,"lc" 'C!Cill %

(~2)1

~litfr Y(~0-hc em ~1~~I<i!<~1cFm~ ~mmt ~ OR" 0fR 50/ ~ ill~I it ~ ~c{~~11cfi

m~~ cmcFl \R11:R ~ ct ~ ct fW1: ~ ~

J1fucFm ~~ ~~, ~ ~ litfr Y(~0-hc ctr

~]4 x 1O-3moldm-3 mqq;Rq{~q(li-fk( ~

%, ~ ~ 0TfucD ~ ~ q{ q"I.,"lc" mWTill ~ I

W ~WK SO/ 0fR R1S ~ ~ ct ~ ~ \ifR

-ijNill~~ir~:sm~ ~ctm~ ~CD/: ~ ~ -ij ~ m ~ CD/: tf %' (tfRDfr 1) I

mlf!ft~m~ >r4rT if ~ \{Wff >r4rT fcniT ~, ifjif ~,~cKi~11

(fwl1nilfiicmrr), 2- lI,~I\'I~\'IlI,lll~il -2- m-1- ~ ~~IHctJ

~ (~~), ~$ITY(~0-hc (fWl1T~),

~I~~I(~P~I (% ~), ~~ctJ ~ (% ~).

mm0~ tJT51~ (fA qT{ ~ fcRrr s® 0f\ff Will

%, if 4Rcn~d l1ffi if ~, 2WJII{F~I, ~~cn ~

~ 2-lI,~I\1~\1l1,J-jI~S~1-2- iWwr -1- mi:r1 ~~IHcn ~ cR

Rfm ~·tR ~~ I~ ~ qr;r if ~ 1Ifr iH(fCF) \311cf~"11Jj1~ 11~~11Jj1 fm ~ ill~I i31Tit eft ctr

~ ~ ~ ct ~~~ ~ \311~11Jj1 ~ ~ litfr~ ~%m~0~-gnJcFlyRCh~d~

cj) ~ ~ if ~ :fcr~T CflTICR TIcn Rm \i'fRIT % I

mq~~ 'it ~ Pr-31DT cET qAT \3fR Pr~ cj) Pr-31DT if

~ ?j~~ fctiT <m- ~ chlyl~.,( cET \3fCTfi em: AA

% I ~ \3fCTfi CJGJcl'cET 0m ~ ~ AA % mq~~~~~AA%I

'q'fturrq 1Fi ~

~ Chlyl81.,(emfcr~~ l:fitcT ~ it ~ ~ cj)

~ R TfIlT;sit fcB Mh-i81R9d%]0 :

~~(%G)=~~x100~ <em: em 'liR

2.0

8.0

14.0

20.0

58.0 36.7

132.0 56.9

224.0 69.1

126.0 55.7

8.7

19.9

33.8

19.0

~ cET T~ m~ fcrfiF1 ~ em 01v:r:H

RTfIlT I

~ ~ (%A) = ?j~~~xl00

~ ~ vr"

~ 2- ~ CJit mtill 'fiTm

(~)x

%G%A %C

]0' mol dm-J 2.0

164.062.124.7

2.8

132.056.919.9

3.6

80.044.412.1

4.4

58.036.78.7

Page 3: ~-mcte-2-~-2'-1-m ~. ~~m~ - NISCAIRnopr.niscair.res.in/bitstream/123456789/3173/1/BVAAP 15(2) 137-140.pdf · 138 2- lI,~I\'I~\'IlI,l-jI~SI -2-m-1-00 ~~IHcn ~-ij~ :sit~ em CIfT1Tc{)

150 I'130 II. "'-_'_'--'0_ ....

~ 110 _ 0 \\ .....•.··.·0 ... •

~ ::[ .--~50G,.",., 'I"o 2 4 6

45- 40

35302520 u

""

150

,l r8

[AMPS] X 102 mol drn')

feR I - 2-lJ>~I~dlJ>ql~sl-2-fi:r~-I-fu ~I"'h'IRCh~ eft~ChTm

-.- %G -.-- %A -.- %C 25130

~20110

<J: ~---- 15::::2c 90(,9 10 ~~ 70

• • 550 -30 0

0 5 10 15[H'J X 103 mol dm·3

feR 2 - i21~i'J01'i ~ eft ~ ChTm

~

262~~

'i 22I 20

j 18u

16 ~

14

. j 12

10

200

1:~!I "f:\i

~:~~lr:\I ~J:l -.

'<,0 f·_·'--,--,-·-f--':!:....-L-L.-..>-l·-'-'--'-'-~I ~~~

o 50 100 150

%G %A %C

193.3 65.9 17.5132.0 56.9 19.9I I 1.4 52.7 23.5738.9 44.1 21.4

I J135 L #/~115 -1

« ~/ I•• f)

1O' 95CJ

I;f!. 75

55 [ .---'-" ..•........ I

I~c -'-'--'---'--j~-L...L...j , , , . I . .,~, , I.J..J . -'-{

25 30 35 40 45 50

13u

1" :::-e, I 0

Temp[':C)

feR 4 - illCf ChTm

feR 6 - ~-~-2-lJ>ChI~<:'ilJ>ql~S.,I-2-fi:r~-I-fu

B0:NRCh ~ ChT~ ~

2- Q~I\il~\ilQ~I~$1 -2- ~ -1- ~ f1~IRCf1 "Qfus etT. g ~ .,.,

~ C@ m: 2- Q}hIM~MQ:r"lI~1-2- '11~\'1 -]- grq-;:r

B0FIl'iCh ~ ~ ~ ~ 1:R ~ ~ ~7TRill ~

fi % I~ m ~ %1~l\l~ \3"lt10ffi Ch'iClG1'i

CRill \JfTill % (Rl jj ]) I

~etT~Cl1Tm:~~~ChT0~1:R ~ crR" m "ChT 01~ fcnm 1fm 0ffi qrm 1fm Fct~ ~ ~ ~ 1:R ~ thllOJlC':< CRill % I W~ ~ ~7TRill ~ et m 0trr% CRfrfch ~ ~

Page 4: ~-mcte-2-~-2'-1-m ~. ~~m~ - NISCAIRnopr.niscair.res.in/bitstream/123456789/3173/1/BVAAP 15(2) 137-140.pdf · 138 2- lI,~I\'I~\'IlI,l-jI~SI -2-m-1-00 ~~IHcn ~-ij~ :sit~ em CIfT1Tc{)

"------ "'"""1' ..-,

L"'"'').-j'J ~~·C(·· 10.1;>0 "'~l

,./- .....----_.. •.,__ __ ..__. ._---f- -0 .~(1)

o

~ 60. a:;S

- 20 :c0:'a:;S

-20800 1000

TGA V5. 1A Dupont 2100

~ ~ B- ~ eft ~~ qcp ;:;ncfr% ~ m~ sm ~ ~ crcn ~ :1f~ ~ ;JfTill % (~3) I

gl$~I\JlO1-3WR etT tri?aTCfiT m : (,I~~'JH ~ eft~ 12 X 10-3 mol dm-3 crcn ~ en:- ~ gf(r~Tdill,~ JfR Ch'iCl;;1'i ~ % CRTifcn 2.11'Q'IqJ"{'Q[ (,1~$I\iH ~ B-~ cmcfl ~k[~~g~1'Q'lg:P'Q1m % \JlT fch ciRr1mlfRT Q{i;i0hc B- ~ cmcfl ~ ~ m % JfR if~ ~ ~ cFr~ ~ ~ cm(f %'(m 2) I

~ 1R Wl<f CfiTm:J~ en:-~ ~ cfim ChT \31~ fcRn -rmT JfR qrm -rmT fch 120 fi'Rc crcn~ ~ ChT '1R" ~ % ~~~ 'C:TC2f ~ % I~ JrcmcIT eft \31fucn liT5IT ~ \3CTW~ cfi m ~

~ ~ fum ircrr ;JfTill % ~ m ~ ~ ChT '1R"

~ \ifRfT % (m 3) I

illll CfiT~ 1R 'JNTcr : ~ ChT illCf ~ en:- m~"):[(Jrl ~ ChT ~ % ;JfTill ~ ~ fch ~~ ,.-!J'" &"'" . <? \J1ll-1l>h'-l1 '11 'l:Jl1T#r2r cfi~ m~ ~ ~ \3IT1:rcn ~ B- ~QT ~%' ~ ~ ChT illCf 40°C crcn ~ en:- ::nfq:trr ~~% (m4)1

~ \?hlllWW: (,I~~\li'i ~ eft ~ ~ ~1/.jlqg'Ql~la'i"[CJ2<:i~ ~ ~ % JfR ~ lfRT Q{i;i0hc cfiW2T J~ ill en:- \3Rf ~ ~ ChT f.'rITurircrr % I if~ ~ B- (,[~i[\li'i \3WR cFr~ cmcfl ~ cfi~~~cm(f%'l~~~~~cfiW2T ~ ~ cFr~ em ~ %'JfR W ~ ~cFr~illwB%''<:i'm~~cFr~wB%'1

1: 80·01illS

·0800 1000

TGA V5. 1A Dupont 2100

m 8 - ~ -lJTCR.'-2-Q}hl~Mll>4[~i'J-2-fi':r~-I-rn

B 0h1 R Cf) ~ Cf)f 'lffiRl1Cf) fcT~~

1543.19

61 J

~II~C-S@WT~~R

~ ~ fclll~ ~ JfR ~-1JT1R- 2-~~1(Tj~(Tj~111~51 -2- irftwr -]- ~ i10bIRCh ~ ChT illCf

~ fcr~~ ill en:-qrm -rmT fch ~ ;:rrq:c - 2-

~~[(Tj~(Tj~l1l~gl -2- irftwr -1- ~ i10bINCh ~ m~ wucn % \3fR ~~ WU fchir \i1'H ~ IN!if\JR cf;gf(r Cf)l1 ~~fu;r %' (m 7,8) I

~1. ~~, if cnt ~, ffi gr QJ1 QCl' fcv:r QJ1 ~ m 388

(1997) 860.

2. W ~ cnTvr gr, & Jl1rri q/2/)iil5Chf'l ~ ft;:rrf,(1987) 130 I.

3. zi'rR cf;, ~ gr QCl'1frt ll> gr QCl'~ r:;q:; gr, fiihilf)'MC?'i(if(

if&s ~$R; 15 (1994) 697.

4. ~ ll>, ~ ~ QCl' 'ffiu:IT ll> m QJ1, m -.:t. 15 ll> cj:) W, (1975)

336-347.

5. ~~ll>, <J.TJJ1~3731, (1956) 349.

6. ~~, i[ TJJ1 ~ 2764, (1956) 843.

7. ~ ~ ll>, i[ TJJ1 ~ 2749, (1956) 277

8. ~~, Jftm ll> ~ cf; QCl' cgciRr cf;, '1i'frrrrr vr#r; 153

(2003) 314.

9. ilMI'MA1 gr T:A' ~ tit it, ~ 3l1q) ~aRi:1R1, 15 (5)(2003) 1105.

10. '~ r:ts ~ chlqMI~{I~v1~H'3m ~ cFitffi 'fcrrft ~~ 1 (1973)